Plain metal would probably be most common for most periods. If you approach the Renaissance, you’ll find that some armor was “blackened” (probably as a rust- preventive measure, like the bluing of firearms), with decorative panels of gilding or even yellow paint (for cheap suits).
Some years ago there was a U.S. touring art exhibit from the Hapsburg armories—I managed to see the show but didn’t purchase the exhibit guide (stupid, stupid, stupid…). If you have a chance to find a used copy for sale (or perhaps look at a library copy) it should more than answer a lot of questions about medieval armor construction, appearance, and color.
Hope this helps a little,
Diego